AP Chemistry — Structure and Properties flashcards
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Units 1–3 of the AP Chemistry course: mass spectra, electron configuration and photoelectron spectra, periodic trends, bonding, Lewis structures and VSEPR, intermolecular forces, gases, solutions, chromatography and Beer's law.
Learn deck · part of AP Chemistry · written against: College Board AP Chemistry Course and Exam Description (nine units). Updated 2026-10-10.
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A mass spectrum of an element shows two peaks: mass 10 at about 20% and mass 11 at about 80% relative abundance. Which element is it, and what is its average atomic mass?Boron, with an average atomic mass of about 10.8 amu: .Atomic Structure and Properties › Moles and Mass Spectra
Why: the average is weighted by abundance, so it sits closer to the more common isotope. -
In the mass spectrum of an element, what do the horizontal position and the height of each peak tell you?Position gives the mass-to-charge ratio, which for singly charged ions is the mass of that isotope; height gives its relative abundance.Atomic Structure and Properties › Moles and Mass Spectra
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Chlorine's average atomic mass is 35.45 and its isotopes are chlorine-35 and chlorine-37. Which isotope is more abundant, and in roughly what ratio?Chlorine-35, in roughly a 3 : 1 ratio (about 76% to 24%), because 35.45 lies about a quarter of the way from 35 to 37.Atomic Structure and Properties › Moles and Mass Spectra
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A student says some chlorine atoms have a mass of 35.45 amu. What is wrong with that statement?No single atom has that mass: 35.45 is a weighted average of isotopes whose individual masses are close to 35 and 37.Atomic Structure and Properties › Moles and Mass Spectra
Watch out: the mass number of an isotope is a whole number; the periodic-table value is an average. -
Which compound has the larger lattice energy, LiF or KF, and why?LiF. Both ions are singly charged, but Li⁺ is much smaller than K⁺, so the ions sit closer together and Coulomb's law gives a stronger attraction.Molecular and Ionic Bonding › Bond Types and Lattices
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Why does an ionic crystal shatter when struck, while a metal bends?Shifting the layers of an ionic lattice lines up like charges, which repel and split the crystal; in a metal the cations sit in a sea of delocalized electrons that keeps bonding them as layers slide.Molecular and Ionic Bonding › Bond Types and Lattices
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Why does solid NaCl not conduct electricity, while molten NaCl and salt water do?Conduction needs mobile charged particles. In the solid the ions are locked in the lattice; melting or dissolving frees them to move.Molecular and Ionic Bonding › Bond Types and Lattices
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n-Pentane boils at 36 °C and neopentane, with the same formula C₅H₁₂, boils near 10 °C. Why?The long, unbranched n-pentane molecules have more surface contact with one another, so their London dispersion forces are stronger; compact, branched neopentane touches its neighbors over a smaller area.Intermolecular Forces and Properties › Intermolecular Forces
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Ethanol and dimethyl ether share the formula C₂H₆O. Which has the higher boiling point, and why?Ethanol (78 °C versus about −24 °C). Its O–H group lets molecules hydrogen-bond to one another, while dimethyl ether has no hydrogen on oxygen and relies on weaker dipole–dipole forces.Intermolecular Forces and Properties › Intermolecular Forces
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Can acetone molecules hydrogen-bond to each other, and can acetone hydrogen-bond with water?Not to each other — acetone has no H bonded to N, O or F. With water, yes: water's O–H hydrogens bond to the lone pairs on acetone's oxygen, which is why the two mix completely.Intermolecular Forces and Properties › Intermolecular Forces
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Review status: Second-reader reviewed, with corrections applied.
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- Topic outline follows the College Board AP Chemistry Course and Exam Description (effective Fall 2024), Units 1–3 (outline only; no course or exam text reproduced).
- OpenStax Chemistry 2e, consulted as a reference; no text copied.
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